The Role of High Base Systems un Vinylation Reactions
DOI:
https://doi.org/10.31150/ajebm.v6i10.2478Keywords:
piperidine, pyridine, morpholine, acetylene, vinylation, homogeneous systemAbstract
The vinylation reaction of piperidine, pyridine and morpholines from nitrogen-containing compounds in highly basic systems has been investigated. The influence of various factors on the course of the process was studied and alternative conditions were found.
Downloads
References
Trofimov B.A. Reaction of acetylene in superbasic media // Uspekhi khimii, 1981, T.50. Issue 2. P.250-255.
Trofimov B.A., Nesterenko R.N., Mikhaleva A.I. New examples of vinylation of NH-heterocycles with acetylene in the KOH-DMSO system // KhGS. -Riga, 1986, -No. 4, -P.481-485.
Nurmanov S.E., Alibekova R.A., Mirkhamitova D.Kh. Catalytic synthesis of N-vinylmorpholine // Science and education of Southern Kazakhstan. Series chemistry, chemical technology. -Kazakhstan, 2003, -No. 35, -P.41-43.
Mirkhamitova D.Kh., Nurmanov S.E., Rashidova S.Sh. Synthesis of N-vinylmorpholine by homogeneous and heterogeneous methods // Bulletin of NUUz. -Tashkent, 2005, -No. 4, -P.52-54.